Current Issue : April-June Volume : 2026 Issue Number : 2 Articles : 5 Articles
Nickel–tungsten carbide (Ni/WC) multi-pass fused cladding layers with different cerium (IV) oxide (CeO2) contents were applied to Cr12MoV cold work tool steel surfaces using the coaxial powder feeding method for laser cladding. Scanning electron microscopy, energy spectrum analysis, X-ray diffraction, and wear experiments were conducted to study how adding CeO2 to change the properties of WC-reinforced Ni-base composite coatings in turn alters the microstructure and properties of Cr12MoV cold work tool steel. The results show that laser cladding is effective when the process parameters are as follows: a power of 1500W, a 24 mm defocusing distance, a 6 mm/s scanning speed, a 5 mmspot diameter, and a powder delivery of 0.1 g/s. Laser-fused cladding coatings are mainly composed of dendrites, crystalline cells, strips, and bulk microstructures. The addition of CeO2 is effective at improving the microstructure and morphology of the coating—the size and distribution of the reinforcing phase change very significantly, and the shape changes from irregular and lumpy to spherical. With a 2% CeO2 content, the enhanced phase, now spherical and white, is more diffusely distributed in the tissue. The maximum microhardness of the composite-coated specimen after the addition of CeO2 is about 986 HV, which is approximately 20% higher than the hardness of the composite coating with no CeO2 added....
The mechanical and microstructural properties of monolithic zirconia ceramics are significant factors for their long-term clinical performance. This study aims to investigate the effects of hydrothermal aging on these properties for the 3Y-TZP, 4Y-TZP, and 5Y-TZP formulations. Specimens were prepared from 3 different zirconia blocks: 3Y-TZP (HT), 4Y-TZP (ST), and 5Y-TZP (XT). Half of the specimens were aged in an autoclave (134 ◦C, 2 bar, 5 h) while the others remained as controls. Three-point flexural strength, Vickers hardness, and surface roughness tests, as well as XRD, AFM, and SEM/EDS analysis, were performed. The material type significantly affected the flexural strength, Vickers hardness, and surface roughness. Aging did not significantly affect the flexural strength or surface roughness but reduced the Vickers hardness in the 3Y-TZP sample. The 3Y-TZP and 5Y-TZP samples displayed the highest and lowest flexural strength, respectively. In the non-aged groups, 3Y-TZP and 5Y-TZP exhibited higher hardness than 4Y-TZP, and after aging, 3Y-TZP displayed the lowest hardness. Further, 5Y-TZP showed the highest surface roughness before and after aging. XRD revealed an increased monoclinic phase in the aged 3Y-TZP and 4Y-TZP. No monoclinic phase was observed in 5Y-TZP. According to AFM measurements, aging led to a smoother surface in 3Y-TZP but increased roughness in 4Y-TZP and 5Y-TZP. SEM/EDS revealed changes in the elemental compositions following aging. According to the results of this study, different material formulations affect the mechanical behavior and microstructural properties of monolithic zirconia ceramics. Further, hydrothermal aging displayed effects on the Vickers hardness and phase transformations....
High-entropy alloys (HEAs) represent one of the most promising emerging material families, particularly for advanced surface engineering applications. In this work, a nearhigh- entropy alloy (near-HEA) coating was produced on a 316L stainless steel substrate using laser metal deposition (LMD) from a powder mixture of Inconel 625, Cr and Mo, without the intentional addition of Fe. Due to dilution from the substrate, the resulting alloy contained elevated Fe content while maintaining Cr, Ni and Mo concentrations within the generally accepted compositional range of HEAs. The deposited layer exhibited a dual-phase microstructure consisting of a face-centered cubic (FCC) phase and a highly distorted tetragonal phase forming a periodic network with a characteristic length scale of several hundred nanometers. The hardness of the coating increased to approximately three times that of the substrate, reaching values of 600–700 HV. To further modify the surface properties, laser-induced periodic surface structures (LIPSS) were generated on the polished coating using femtosecond pulsed laser irradiation at different energy densities. The morphology and subsurface structure of the resulting periodic patterns were investigated by scanning electron microscopy. LIPSS with characteristic dimensions ranging from the micrometer to nanometer scale were successfully produced. Cross-sectional analyses revealed that the underlying dual-phase microstructure remained continuous within the laser-structured regions, indicating that LIPSS formation occurred predominantly via metallic ablation without significant phase transformation or amorphization. These results demonstrate the combined applicability of LMD and femtosecond laser structuring for producing mechanically enhanced, micro- and nanostructured near-HEA coatings with potential for advanced surface-related functionalities....
Fiber-reinforced laminates composed of a thermoset matrix have seen widespread use in industries such as the aerospace, wind power, and automotive industries, due to their strength-to-weight ratios and ease of formability. For optimal performance, the instantaneous cure state must be sufficient such that the component will not deform during or after molding, a state that can vary based on many manufacturing-related factors. Thus, monitoring the cure process non-destructively in situ is key to manufacturing composite laminates to achieve the as-designed properties while balancing the cycle time reduction. The current work presents a pulse-echo ultrasound method to correlate the acoustic waveform to the thermoset resin cure state and the instantaneous structural properties, specifically the resin storage and loss moduli. This latter information provides a fabricator knowledge of when a part can be successfully demolded, allowing for optimizing part cycle times. The present paper provides the results for the neat resin specimen and fiberglass specimen impregnated with the same resin system. The results provide a direct correlation between the acoustic and the viscoelastic properties. Interestingly, it is noted that there is a direct correlation between the peak signal attenuation and the peak gelation of the material, thus providing a means to predictively schedule the demolding time while maintaining proper curing cycles....
Achieving thickness uniformity is a critical challenge in superplastic forming (SPF) of hemispherical shells, as standard constant-thickness blanks suffer from excessive thinning at the pole. While the literature suggests using variable thickness blanks to mitigate this issue, existing solutions often rely on complex, non-linear profiles that are expensive and difficult to manufacture. This work proposes a cost-effective, truncated conical blank design (linearly variable thickness) to optimize material distribution. The approach combines Finite Element Method (FEM) analysis and experimental validation on AZ31 magnesium alloy. The study demonstrates that the optimized truncated conical profile (α = 0.2) yields superior structural quality, drastically reducing the thinning factor to 9%. This represents a significant improvement compared to the ~14% thinning observed with conical profile (α = 0) blanks and outperforms constant-thickness blanks (30%). These results demonstrate that a simplified, easily machinable blank geometry can effectively address the thinning problem, providing a practical solution for industrial SPF applications....
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